The research data comprises: 1. An excel file containging all x-y data points for all graphs in the main paper 2. An excel file containging all x-y data points for all graphs in the Supplementary Information The Supplementary Information comprises: 1. Device fabrication details 2. Description of the contact structures 3. Characterisation of the materials (optical transmission, absorption coefficient, Tauc plot, photoemission determination of band edge) 4. Capacitance-voltage mathematics for one-sided and two-sided junctions 5. Capacitance-voltage results (Mott-Shottky plot) 6. Inferred band diagrams for the heterojunction The doi of the full paper is 10.1109/JPHOTOV.2020.2981805